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Anomalous dehydration of 2-phenylindole-3-carboxamide to 2-phenylindole-3-carbonitrile by lithium aluminum hydride

 

作者: TonsonAbraham,   AlbertJ.Sicree,  

 

期刊: Monatshefte für Chemie / Chemical Monthly  （Springer Available online 2004）
卷期: Volume 113, issue 8  

页码: 1063-1066

 

ISSN:0026-9247

 

年代: 2004

 

DOI:10.1007/BF00799248

 

出版商: Springer_Vienna-Vienna

 

数据来源: Springer

 

摘要:

Steric factors have been shown to be responsible for the anomalous dehydration of 2-phenylindole-3-carboxamide (1) to 2-phenylindole-3-carbonitrile (3) by lithium aluminum hydride. This steric effect was also reflected in the reactions of 2-phenylindole (4) and its derivatives.

 

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