Unpolymerized Surface Layers on Sealants
作者:
RuyterIvar Eystein,
期刊:
Acta Odontologica Scandinavica
(Taylor Available online 1981)
卷期:
Volume 39,
issue 1
页码: 27-32
ISSN:0001-6357
年代: 1981
DOI:10.3109/00016358109162255
出版商: Taylor&Francis
关键词: Dental polymers;oxygen inhibition;substituent constants;microscopy
数据来源: Taylor
摘要:
Oxygen inhibits radical polymerization, and for the present investigation, the thickness of the resulting unpolymerized surface layer on various proprietary dental polymers was measured by a microscopic technique. The inhibition depth of the polymerized resins varied from 7 to 84μm. Resin systems with the tertiary aromatic amine 3, 4-xylyldiethanolamine as the activator had a thinner unpolymerized layer than those with p-tolyldiethanolamine. Increased viscosity also resulted in reduced thickness of the unpolymerized films. UV-light cured resins had thinner inhibited layers than those of comparable viscosity with a peroxide-amine initiator system. However, the thinnest unpolymerized film was seen with a chemically activated resin system containing acetone.This investigation has shown that the thickness of the unpolymerized film on cured dental resins is related to the composition and the initiating system.
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