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The distribution of fluctuations of the total dipole moment in polar liquids

 

作者: P.G. Kusalik,  

 

期刊: Molecular Physics  (Taylor Available online 1993)
卷期: Volume 80, issue 2  

页码: 225-231

 

ISSN:0026-8976

 

年代: 1993

 

DOI:10.1080/00268979300102231

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The distribution of fluctuations of the total dipole moment in polar liquids is characterized. The functional form of the probability distribution function,P(g), wheregis proportional to the square of the total moment and its average value is directly related to the static dielectric constant, is empirically determined. A formal justification of the functional form is then developed and implications to the calculation of the dielectric constant in computer simulations are discussed.

 

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