The distribution of fluctuations of the total dipole moment in polar liquids
作者:
P.G. Kusalik,
期刊:
Molecular Physics
(Taylor Available online 1993)
卷期:
Volume 80,
issue 2
页码: 225-231
ISSN:0026-8976
年代: 1993
DOI:10.1080/00268979300102231
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The distribution of fluctuations of the total dipole moment in polar liquids is characterized. The functional form of the probability distribution function,P(g), wheregis proportional to the square of the total moment and its average value is directly related to the static dielectric constant, is empirically determined. A formal justification of the functional form is then developed and implications to the calculation of the dielectric constant in computer simulations are discussed.
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