A Viscometric Approach to the Study of the Kinetics of Polyurethane Reactions
作者:
Reji John,
EbyThomas Thachil,
N.R. Neelakantan,
N. Subramanian,
期刊:
Polymer-Plastics Technology and Engineering
(Taylor Available online 1991)
卷期:
Volume 30,
issue 5-6
页码: 545-557
ISSN:0360-2559
年代: 1991
DOI:10.1080/03602559108019220
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Kinetics and rheological studies were carried out on polyurethane reactions involving a new polyol and TDL Conversion of isocyanate by uncatalyzed polymerization under isothermal conditions was monitored by IR spectrometry and titration. Viscosity changes of the reaction mixture were followed by a digital cone-and-plate viscometer under identical conditions. Conversion and viscosity were found to follow a power relationship. A relationship involving the order of the reactionnthat connects the viscosity with time was derived. This provides a new viscometric method to find the order of the reaction. The order of the reaction determined by this method was very close to the values obtained by a fractional-life method already reported.
点击下载:
PDF (385KB)
返 回