The entropy of a glass

 

作者: RobinJ. Speedy,  

 

期刊: Molecular Physics  (Taylor Available online 1993)
卷期: Volume 80, issue 5  

页码: 1105-1120

 

ISSN:0026-8976

 

年代: 1993

 

DOI:10.1080/00268979300102911

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

From the thermodynamic viewpoint the glass transition is a second-order change: there is no latent heat involved, so the entropy varies continuously through the transition. But the transition is not a reversible process. A simulation study of the hard-sphere fluid shows that the statistical entropy, defined in terms of the configuration integral, decreases by 0·20 ± 0·03Nkwhen it forms a glass, which indicates that a system ofNhard spheres can form about exp (0·2N) glasses. For the system ofN= 256 spheres studied there are about 1022distinct glasses.

 

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