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Short-range disorder in lanthanum-doped lead titanate ceramics probed by Raman scattering

 

作者: E. C. S. Tavares,   P. S. Pizani,   J. A. Eiras,  

 

期刊: Applied Physics Letters  (AIP Available online 1998)
卷期: Volume 72, issue 8  

页码: 897-899

 

ISSN:0003-6951

 

年代: 1998

 

DOI:10.1063/1.120929

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Raman scattering has been used to probe short-range structural information on lanthanum-doped lead titanate ceramics(LaxPb1−xTiO3)forx,ranging from 0.0 to 0.30. In highly doped samples(x>0.27),x-ray diffraction measurements indicate a cubic structure, although measurements of Raman scattering at temperatures above and below the tetragonal to cubic transition showed a residual short-range structural disorder in the cubic phase. Moreover, for these highly lanthanum-doped samples, a well-defined temperature-induced ferro–paraelectric phase transition disappears, which suggests a relationship between local disorder and relaxor behavior in this material. ©1998 American Institute of Physics.

 

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