Short-range disorder in lanthanum-doped lead titanate ceramics probed by Raman scattering
作者:
E. C. S. Tavares,
P. S. Pizani,
J. A. Eiras,
期刊:
Applied Physics Letters
(AIP Available online 1998)
卷期:
Volume 72,
issue 8
页码: 897-899
ISSN:0003-6951
年代: 1998
DOI:10.1063/1.120929
出版商: AIP
数据来源: AIP
摘要:
Raman scattering has been used to probe short-range structural information on lanthanum-doped lead titanate ceramics(LaxPb1−xTiO3)forx,ranging from 0.0 to 0.30. In highly doped samples(x>0.27),x-ray diffraction measurements indicate a cubic structure, although measurements of Raman scattering at temperatures above and below the tetragonal to cubic transition showed a residual short-range structural disorder in the cubic phase. Moreover, for these highly lanthanum-doped samples, a well-defined temperature-induced ferro–paraelectric phase transition disappears, which suggests a relationship between local disorder and relaxor behavior in this material. ©1998 American Institute of Physics.
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