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Double Resonance Technique for the Elimination of Proton Spin‐Spin Splitting in High Resolution PMR Spectra

 

作者: Reinhold Kaiser,  

 

期刊: Review of Scientific Instruments  (AIP Available online 1960)
卷期: Volume 31, issue 9  

页码: 963-965

 

ISSN:0034-6748

 

年代: 1960

 

DOI:10.1063/1.1717118

 

出版商: AIP

 

数据来源: AIP

 

摘要:

The double resonance technique aims at removing the effect of spin‐spin coupling by the application of a strong rf field at the resonance frequency of the disturbing nucleus in addition to the weak rf field used for observation of the NMR spectrum. A method is described whereby the weak rf field is obtained by a small audio frequency modulation of the magnetic field strength. This method is applicable to chemically nonequivalent groups of hydrogen nuclei to simplify the interpretation of high resolution proton magnetic resonance spectra. Two examples are given.

 

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