首页   按字顺浏览 期刊浏览 卷期浏览 Simple Stereocontrolled Synthesis of Methyl 2-Deoxy-d-erythro-hexopyranosid-4-uloses, T...
Simple Stereocontrolled Synthesis of Methyl 2-Deoxy-d-erythro-hexopyranosid-4-uloses, Thromboxane B2(TXB2) Precursors, fromd-Galactose

 

作者: Oscar Moradei,   Cecile du Mortier,   AliciaFernández Cirelli,   Joachim Thiem,  

 

期刊: Journal of Carbohydrate Chemistry  （Taylor Available online 1995）
卷期: Volume 14, issue 4-5  

页码: 525-532

 

ISSN:0732-8303

 

年代: 1995

 

DOI:10.1080/07328309508005355

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The stereospecific synthesis of methyl 3-O-benzoyl-6-O-(tert-butyldiphenylsilyl)-2-deoxy-α-d-erythro-hexopyranosid-4-ulose (5) - a Thromboxane B2(TXB2) precursor -starting from D-galactose is described. Facile and established methods including selective benzoylation, oxidation-elimination and a stereocontrolled hydrogenation (Pd/charcoal) were employed effectively.

 

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