Preparation of a Chelating Polymeric Membrane and Application to Uphill Transport
作者:
JamesA. Cox,
Ewa Dabek-zlotorzynska,
Krystyna Brajter,
期刊:
Analytical Letters
(Taylor Available online 1987)
卷期:
Volume 20,
issue 8
页码: 1149-1156
ISSN:0003-2719
年代: 1987
DOI:10.1080/00032718708064599
出版商: Taylor & Francis Group
关键词: chelating membrane;uphill transport;metal enrichment;facilitated transport
数据来源: Taylor
摘要:
Modification of an anion-exchange membrane by (1-(2-arsono-phenylazo))-2-hydroxy-3,6-naphthalenedisulfonic acid (thoron) results in a membrane that can chelate metals. The high affinity of the disulfonate for the anion-exchange sites together with molecular adsorption of the aromatic thoron onto the polymers yields a system that is stable in strong acids at or below 1 M. By employing a relatively high pH sample (5-9) in conjunction with an acidic stripping solution (0.2 - 1.0 M HCl), uphill transport of Cu(II) and Zn(II) was accomplished. The transport rate was increased by means (lower chelating capacity and the use of a chelate-forming aid on in the stripping solution) of promoting the volume diffusion mechanism of membrane transport. With a 0.05 mmol per dry gram chelating capacity and a 0.1 M EDTA stripping solution (pH 6.5), an enrichment factor of 16 was observed in a one-hour experiment with a 200 mL sample, 11 cm2membrane, and 5 mL stripping solution. This value compares favorably with those obtained by other uphill transport modes under the same conditions.
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