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The structure and partial synthesis of imbricatine, a benzyltetrahydroisoquinoline alkaloid from the starfishDermasteriasimbricata

 

作者: David L. Burgoyne,   Shichang Miao,   Charles Pathirana,   Raymond J. Andersen,   William A. Ayer,   Peter P. Singer,   William C. M. C. Kokke,   Donald M. Ross,  

 

期刊: Canadian Journal of Chemistry  （NRC Available online 1991）
卷期: Volume 69, issue 1  

页码: 20-27

 

ISSN:0008-4042

 

年代: 1991

 

DOI:10.1139/v91-004

 

出版商: NRC Research Press

 

数据来源: NRC

 

摘要:

The structure of imbricatine (1), a cytotoxic metabolite of the starfishDermasteriasimbricata, has been determined by spectroscopic analysis and chemical degradation. Synthesis of model compounds7and18provided evidence for the absolute configuration and constitution of the benzyltetrahydroisoquinoline substructure of imbricatine.Keywords: imbricatine, asteroid, alkaloid.

 

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