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Paramagnetic resonance of phosphorescent tetramethylpyrazine

 

作者: M.S. de Groot,   I.A.M. Hesselmann,   F.J. Reinders,   J.H. van der Waals,  

 

期刊: Molecular Physics  (Taylor Available online 1975)
卷期: Volume 29, issue 1  

页码: 37-48

 

ISSN:0026-8976

 

年代: 1975

 

DOI:10.1080/00268977500100041

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Electron paramagnetic resonance spectra have been obtained of tetramethylpyrazine in its lowest (ππ*) triplet state in several rigid matrices. Some unusual observations were made :1.(1) In a durene crystal host the in-plane zero-field principal axes are not parallel to the molecular symmetry axes.2.(2) In rigid glass solution the zero-field parameters are strongly dependent on solvent polarity.

 

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