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Polymer network structure and electro-optic performance of polymer stabilized cholesteric textures II. The effect of UV curing conditions

 

作者: I. DIERKING,   L. L. KOSBAR,   A. C. LOWE,   G. A. HELD,  

 

期刊: Liquid Crystals  (Taylor Available online 1998)
卷期: Volume 24, issue 3  

页码: 397-406

 

ISSN:0267-8292

 

年代: 1998

 

DOI:10.1080/026782998207217

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The effect of UV curing intensity and curing time on the electro-optic behaviour and network morphology of reverse mode polymer stabilized cholesteric textures (PSCTs) has been studied. Scanning electron micrographs indicate that increasing the curing intensity generally results in a more open polymer network characterized by a larger average void size, while the morphology of the individual strands remains largely unchanged. In addition, as the polymerization process proceeds, voids within the network are observed to decrease in size. PSCTs with sufficiently large network voids exhibit a two-stage switching behaviour consistent with a model in which the cholesteric liquid crystal is divided between two distinct environments one in which the liquid crystal is strongly dominated by the polymer network, the other in which a bulk-like behaviour, comparable to the unstabilized cholesteric material, is observed.

 

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