Kinetics and Equilibria of Proton Exchange in the Lowest Excited Singlet State of 1-Hydroxyfluorene in Aqueous Solutions
作者:
A.Muñoz De La Peña,
A. Fernández-Gutiérrez,
S.G. Schulman,
期刊:
Analytical Letters
(Taylor Available online 1985)
卷期:
Volume 18,
issue 19
页码: 2489-2495
ISSN:0003-2719
年代: 1985
DOI:10.1080/00032718508082587
出版商: Taylor & Francis Group
关键词: 1-Hydroxyfluorene;fluorescence;excited state proton transfer
数据来源: Taylor
摘要:
The determination of the rate constants for proton exchange in the lowest excited singlet state of 1-hydroxyfluorene from the pH dependences of its fluorescence spectra is performed in aqueous solutions. Also, the excited singlet state acidity constant of this compound, obtained from fluorescence titration of both conjugate acid and base forms an from the averages of the absorption and fluorescence maxima, is reported.
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