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Strain-induced crystallization in cis- and trans-polyisoprene blends: Apparent crystallinity

 

作者: A. Manzur,  

 

期刊: Journal of Macromolecular Science, Part B  (Taylor Available online 1989)
卷期: Volume 28, issue 3-4  

页码: 329-337

 

ISSN:0022-2348

 

年代: 1989

 

DOI:10.1080/00222348908215227

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Strain-induced crystallization (SIC) was studied in blends of cis-l,4-polyisoprene (hevea rubber) and synthetic trans-1,4-polyisoprene (t-PI) using the wide-angle x-ray scattering technique. Uncrosslinked solution blends were uniaxially stretched at room temperature, and the dependence of the apparent crystallinity on elongation and t-PI content was analyzed. With increasing amounts of t-PI, both the onset of SIC phenomenon and the rupture occur at smaller elongations. These results are in accord with those obtained previously on true stress and birefringence.

 

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