2-Glycosylchromene Derivatives
作者:
Jean M. J. Tronchet,
Sami Zerelli,
Gérald Bernardinelli,
期刊:
Journal of Carbohydrate Chemistry
(Taylor Available online 1999)
卷期:
Volume 18,
issue 3
页码: 343-359
ISSN:0732-8303
年代: 1999
DOI:10.1080/07328309908544000
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Treated with salicylaldehyde or its 5-methoxy derivative, a series of blocked terminal(E)-nitroenoses underwent a condensation reaction leading in fair to good yields to blocked 2-glycosyl-3-nitro-2H-chromene derivatives. Treated with cyanide, the nitro derivatives afforded 4-cyano-2-glycosyl-2H-chromenesviaan addition-elimination reaction. These two types of chromenes bearing an electron-withdrawing group have been previously shown to have antiviral or cytotoxic properties related to their electrophilicity.
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