Leaf structure and function are shown to result in distinctive variations in the absorption and reflection of solar radiation from plant canopies. The leaf properties that determine the radiation-interception characteristics of plant canopies are directly linked to photosynthesis, stomatal resistance and evapotran-spiration and can be inferred from measurements of reflected solar energy. The effects of off-nadir viewing and atmospheric constituents, coupled with the need to measure changing surface conditions, emphasize the need for multitemporal measurements of reflected radiation if primary production is to be estimated