Investigations of the EPR parameters and the local structures for V2+, Ni2+and Mn2+ions in CsMgCl3crystal
作者:
Z. Wen-Chen,
期刊:
Radiation Effects and Defects in Solids
(Taylor Available online 1992)
卷期:
Volume 124,
issue 2
页码: 233-238
ISSN:1042-0150
年代: 1992
DOI:10.1080/10420159208220195
出版商: Taylor & Francis Group
关键词: electron paramagnetic resonance;crystal-field theory;local lattice relaxation;V2+;Ni2+;Mn2+;CsMgCl3
数据来源: Taylor
摘要:
The EPR parameters (D, g‖andg⊥) for V2+, Ni2+and Mn2+ions in linear-chain lattice CsMgCl3at 77 K have been studied from the crystal-field theory. From these studies, one can find that the local lattice relaxation occurs in the vicinity of these paramagnetic impurity ions. The bonding angles β of MCl4-6groups in the cases of V2+and Ni2+ions are determined quantitatively from EPR data and in the case of Mn2+ion, it is estimated qualitatively. These results support the opinion that the [MX−3]nchains in one-dimensional AMX3, lattice are easily deformed to accommodate impurity ions.
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