Surface diffusion of adsorbable gases through porous media
作者:
L. A. Roybal,
S. I. Sandler,
期刊:
AIChE Journal
(WILEY Available online 1972)
卷期:
Volume 18,
issue 1
页码: 39-42
ISSN:0001-1541
年代: 1972
DOI:10.1002/aic.690180108
出版商: American Institute of Chemical Engineers
数据来源: WILEY
摘要:
AbstractAn activated diffusion, or site‐hopping, mechanism is used to describe surface diffusion of gases through porous media. This analysis provides a useful and accurate method for correlating data at submonolayer coverages on energetically heterogeneous surfaces. The data needed to use this correlation are surface area and pore structure of the adsorbent, adsorption isotherms at two or more temperatures, and the activation energy for migration. The former quantities are easily determined from Knudsen diffusion and adsorption measurements, while the activation energy can be found from a single permeability measurement. Predictions made in this way show excellent agreement with experimental dat
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