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Synthesis and Dimerization of Bicyclo [4.4.1] undec‐1 (11)‐ene, a Bridgedtrans‐Cycloheptene

 

作者: Konrad B. Becker,   Jacques L. Chappuis,  

 

期刊: Helvetica Chimica Acta  （WILEY Available online 1979）
卷期: Volume 62, issue 1  

页码: 34-43

 

ISSN:0018-019X

 

年代: 1979

 

DOI:10.1002/hlca.19790620106

 

出版商: WILEY‐VCH Verlag GmbH

 

数据来源: WILEY

 

摘要:

AbstractThe synthesis of bicyclo [4.4.1] undec‐1 (11)‐ene (5) by intramolecularWittigreaction is described. TheBredtolefin could not be isolated, but dimerized rapidly to a novel compound15containing a cyclopropane ring. The olefin5was trappedin situby 2,5‐diphenylbenzo [c]

 

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