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Morphological study of a chiral polymer network in a nematic liquid crystal from a concentration gradient

 

作者: MICHEL MITOV,   ALAIN BOUDET,   PIERRE SOPENA,   PIERRE SIXOU,  

 

期刊: Liquid Crystals  (Taylor Available online 1997)
卷期: Volume 23, issue 6  

页码: 903-910

 

ISSN:0267-8292

 

年代: 1997

 

DOI:10.1080/026782997207849

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

A contact preparation is made between a cholesteric photocrosslinkable material and a standard nematic liquid crystal. The concentration and the anisotropy progressively and homogeneously vary along a direction perpendicular to the diffusion front. On the basis of scanning electron microscopy investigations, comparisons are made between the modifications of the polymer network from a sample region rich in one component to the complementary region rich in the other. Such a preparation offers the opportunity to visualize the morphological transformations when a phase transition occurs and the morphologies intrinsic to textures intermediate between well-classified mesomorphic textures. Scanning electron microscopy texture observations are made in parallel with those by optical microscopy in order to make the connection with the mesomorphic textures, which therefore act as indicators during the subsequent SEM investigations.

 

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