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Batch and Continuous Emulsion Copolymerization of Ethyl Acrylate and Methacrylic Acid

 

作者: GlennL. Shoaf,   GaryW. Poehlein,  

 

期刊: Polymer-Plastics Technology and Engineering  (Taylor Available online 1989)
卷期: Volume 28, issue 3  

页码: 289-317

 

ISSN:0360-2559

 

年代: 1989

 

DOI:10.1080/03602558908048601

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Emulsion copolymerization of a moderately water-soluble monomer (ethyl acrylate) with a completely water-soluble monomer (methacrylic acid) was initially examined in a batch reaction system. The reaction rates, copolymer composition, and physical properties of the latex product were characterized. Batch reactions were run with various monomer ratios. The latex stability was strongly dependent on both the temperature and the overall fractional conversion. Several continuous processes involving a tubular reactor and/or a continuous stirred-tank reactor were designed and utilized so as to produce a latex product with properties similar to the batch product.

 

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