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Kinetics and mechanism of high-temperature decomposition of di-methyl-di (tert-butyl-peroxy) silane

 

作者: A.Ya.Gerchikov,   S.R.Gizatullina,   N.V.Yablokova,   Yu.A.Aleksandrov,   V.S.Martemyanov,  

 

期刊: Reaction Kinetics and Catalysis Letters  （Springer Available online 2005）
卷期: Volume 41, issue 1  

页码: 187-191

 

ISSN:0133-1736

 

年代: 2005

 

DOI:10.1007/BF02075502

 

出版商: Springer_Netherlands-Dordrecht

 

数据来源: Springer

 

摘要:

Kinetic parameters and rate constants for initiation reaction during thermal decomposition of di-methyl-di (tert-bytylperoxy) silane in tetravalerate-pentaerythrol solution have been determined at temperatures ranging from 170 to 220°C. It has been established that tert-butyl hydroperoxide, the product of homolytic peroxysilane decomposition, takes part in the initiation reaction

 

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