The zero‐order kinetics of acetaldehyde thermal generation from polyethylene terephthalate
作者:
G. W. Halek,
期刊:
Journal of Polymer Science: Polymer Symposia
(WILEY Available online 1986)
卷期:
Volume 74,
issue 1
页码: 83-92
ISSN:0360-8905
年代: 1986
DOI:10.1002/polc.5070740110
出版商: Wiley Subscription Services, Inc., A Wiley Company
数据来源: WILEY
摘要:
AbstractThe thermal decomposition of polyethylene terephthalale has been examined by healing isothermally in a high‐mass reaction chamber and collecting the evolved acetaldehyde on a GC column for quantization. Kinetics were determined at lime intervals up to 1 h for temperatures 225°C, 240°C, 250°C, 260°C, 265°C, 270°C, 280°C, and 300°C. The rate of acetaldehyde evolution was found to be directly proportional to time of reaction at each temperature, thus fitting a zero‐order reaction. The Arrhenius plot of the data yielded a straight line above the melting point with a slope different from the straight line for reaction rates below the melting point. The change in slopes occurred around the crystalline melting point. The following thermodynamic values were found above and below the melting point, respectively:EA, 37.5 and 8.2 kcal/mol; ΔSA, + 1.5 and −54 e.u.;A, 0.68 × 1014and 0.43 × 102sec−1. Possible mechanistic implicat
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