Cationic Polymerization of Cyclic Dienes. VI. Cationic Copolymerization of Cyclopentadiene and α-Methylstyrene
作者:
Yukio Imanishi,
Kazuo Hara,
Shinzo Kohjiya,
Seizo Okamura,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1968)
卷期:
Volume 2,
issue 8
页码: 1423-1439
ISSN:0022-233X
年代: 1968
DOI:10.1080/10601326808051909
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The cationic copolymerizations of α-methylstyrene and cyclopentadiene were carried out and the monomer reactivity ratios were determined. It was found that cyclopentadiene was more reactive than α-methylstyrene, and that the effect of solvent polarity on the monomer reactivity ratio was small. It was deduced from the pKBH+values of cations pertinent to the present investigation that there is little difference between the stabilities of cyclopentenyl cation and cumyl cation. The present experiment seems to be the first example showing that there is little solvent effect even in the copolymerization between monomers of dissimilar structures, if the stabilities of cations are similar.
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