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Viscoelastic properties of colloidal gels

 

作者: C. J. Rueb,   C. F. Zukoski,  

 

期刊: Journal of Rheology  (AIP Available online 1997)
卷期: Volume 41, issue 2  

页码: 197-218

 

ISSN:0148-6055

 

年代: 1997

 

DOI:10.1122/1.550812

 

出版商: The Society of Rheology

 

关键词: Colloidal gel;Gel, colloidal;Interparticle force;Aggregation;Fractal dimension

 

数据来源: AIP

 

摘要:

The microstructure and scaling of mechanical properties of dense colloidal gels were investigated as a function of volume fraction and strength of interparticle attraction. Gels were reversibly formed by cooling suspensions of octadecyl silica particles in decalin or tetradecane. Shear history independence of mechanical properties was ensured by preshearing the suspensions in the gelled state. Gelation resulted in suspensions with apparent fractal dimensions of 1.4. Shear densification resulted in an apparent fractal dimension of 2.5 for structures containing many particles. When the gelled suspension was presheared, just after the shear rate was set to zero, elastic moduli were small. Over time, the moduli recovered to a time independent value,G∞′,at a rate α. When measured over a wide range of volume fraction, φ, and strength of interparticle attraction,G∞′,α, and the strain limiting the extent of linear response to oscillatory deformations,γM,fell onto master curves when plotted as a function ofφ/φGfor1.1<φ/φG<5. HereφGis the gel volume fraction that varied from 0.11 to 0.59 for temperatures studied.

 

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