JSSN 0300-9599 JCFTAR 85(8) 1881-2647 (1 989) 1881 1897 1907 1921 1933 1945 1963 1979 199 200 20 1 202 1 2035 2047 2055 207 1 2079 2087 JOURNAL OF THE CHEMICAL SOCIETY FARADAY TRANSACTIONS I Physical Chemistry in Condensed Phases Thermodynamics of the Transition State and the Application to Interfacial Reactions D. G. Hall Tin Oxide Surfaces. Part 18.-Infrared Study of the Adsorption of very low Levels (20-50 ppm) of Carbon Monoxide in Air on to Tin(1v) Oxide Gel P. G. Harrison and A. Guest Tin Oxide Surfaces. Part 19.-Electron Microscopy, X-Ray Diffraction, Auger Electron and Electrical Conductance Studies of Tin(1v) Oxide Gel P. G. Harrison and M. J. Willett Tin Oxide Surfaces. Part 20.-Electrical Properties of Tin(rv) Oxide Gel : Nature of the Surface Species Controlling the Electrical Conductance in Air as a Function of Temperature Interaction between Amine Oxide Surfactant Layers Adsorbed on Mica C.E. Herder, P. M. Claesson and P. C. Herder Zeolites treated with Silicon Tetrachloride Vapour. Part 5.4atalytic Cracking of n-Hexane M. W. Anderson, J. Klinowski, J. M. Thomas and M. T. Barlow Further Electron Spin Resonance Studies of RhNa-X. Effects of Carbon Monoxide, Hydrogen and Oxygen A. Sayari, J. R. Morton and K. F. Preston Photocurrent Kinetics in Metal Phthalocyanine Crystals, Films and Pellets G. S. Bahra, A. V. Chadwick, J. W. Couves and J. D. Wright Characterization of Supported Ni'CO(TAP), (n < 3) Complexes by the CO Stretching Vibration. Electron-donating Effect of Trialkylphosphine Ligands M. Kermarec, C. Lepetit, F.X. Cai and D. Olivier Role of Solvent Dynamics on Kinetics of Electro-oxidation of Ferrocene at Platinum Electrode Sequential Oscillations in the Belousov-Zhabotinski System with Ascorbic Acid-Acetone/Cyclohexanone as the Mixed Organic Substrate R. P. Rastogi, I. Das and A. Sharma Chemical Environments around Active Sites and Reaction Mechanisms for Deuterium-Acrolein Reaction over Ir/Nb,O, in Normal and SMSI States H. Yoshitake, K. Asakura and Y. Iwasawa Longitudinal Relaxation of Protons in Partially Deuterated [A1(H,0),I3+ J. W. Akitt, J. M. Elders and 0. W. Howarth Redox Catalysis. Theory for a Nernstian Reaction Coupled to an Irreversible Reaction Kinetic Study of the Oxidation of Water by CerV Ions Mediated by Activated Ruthenium Dioxide Hydrate Mechanistic Studies of Capillary Processes in Porous Media.Part 1 .-Prob- abilistic Description of Porous Media V. Mayagoitia, M. J. Cruz and F. Rojas Mechanistic Studies of Capillary Processes in Porous Media. Part 2.-Con- struction of Porous Networks by Monte-Carlo Methods M. J. Cruz, V. Mayagoitia and F. Rojas The Peptide-Urea Interaction. Excess Enthalpies of Aqueous Solutions of N- Acetylamides of Amino Acids and Urea at 298.15 K G. Barone, G. Castronuovo, P. Del Vecchio and C. Giancola P. G. Harrison and M. J. Willett S. U. M. Khan A. Mills and N. McMurray A. Mills and N. McMurray2099 21 13 2127 2141 2149 2159 2173 2185 2199 221 1 2229 224 1 2249 2255 2273 2285 2297 2309 2327 2335 2347 Contents Chemical Relaxation and Equilibrium Studies associated with the Binding of Anionic Surfactants to Neutral Polymers N.Takisawa, P. Brown, D. Bloor, D. G. Hall and E. Wyn-Jones The Formation of a Well Defined Rhodium Dicarbonyl in Highly Dealuminated Rhodium-exchanged Zeolite Y by Interaction with CO H. Miessner, I. Burkhardt, D. Gutschick, A. Zecchina, C. Morterra and G. Spoto Physico-chemical Characterization and Framework Topology of Zeolite ZSM- 20 V. Fulop, G. BorbCly, H. K. Beyer, S. Ernst and J. Weitkamp Densimetric and Viscosimetric Investigations of NaI in Hexamethylphos- phoramide-Water Mixtures at 293.15, 298.15 and 303.15 K S. Taniewska- Osinska and M. Joiwiak Temperature-dependent Conformational Analysis of Gentiobiose Octa-acetate in Solution. Proton and Carbon Nuclear Magnetic Relaxation Study C. Rossi, S.Ulgiati and N. Marchettini Exchange Reactions of Alkanes containing Quaternary Carbon Atoms over Supported Metal Catalysts Reactions of Unsaturated Hydrocarbons on Rutile and Anatase B. I. Brookes, R. Bird, C. Kemball and H. F. Leach Ionic Solvation in Water-Co-solvent Mixtures. Part I 8.-Free Energies of Transfer of Single Ions from Water into Water-2-Methoxyethanol Mixtures K. H. Halawani and C. F. Wells Electron Spin Resonance Study of the Interaction of Oxygen with Ag/SiO, Y-P. Wang, C-t. Yeh and S-H. Chien Complex Formation and Self-association in Ternary Mixtures. Apparent Heat Capacities for Alcohol-Methyl Acetate-Hydrocarbon and Acetone-Chloro- form-Cyclohexane M. Costas, Z. Yao and D. Patterson Vapour Pressure of Butane from 173 to 280 K W. D. Machin and P.D. Golding Kinetic Salt Effects on the Reaction between the [ 1,3,6,8,10,13,16,19-Octa- azabicyclo(666)icosane]Cobalt( 111) Ion, C~(sep)~+, and the Hexa-aquochrom- ium(r1) Ion Redox and Acidic Properties of the Borate Radical B(0H);. A Flash Photolysis Study S. Padmaja, V. Ramakrishnan, J. Rajaram and J. C. Kuriacose Channel-elec t rode Vol tammet ry . Waves hape Analysis of the Curren t-Vol tage Curves of EC, and DISP2 Processes R. G. Compton and M. B. G. Pilkington Flat - Vertical Transitions of Fluoranthene Molecules adsorbed on a Mercury Electrode Transference Number Measurements of Silver Nitrate in Pure and Mixed Solvents using the Electromotive Force Method D. S. Gill and M. S. Bakshi Transference Number, Conductance and Viscosity Studies of some 1 : 1 Electrolytes in Pyridine-Methanol Mixtures at 25 "C D.S. Gill and M. S. Bakshi Formation of Hydrocarbons in the Electrochemical Reduction of Carbon Dioxide at a Copper Electrode in Aqueous Solution Y. Hori, A. Murata and R. Takahashi Structure of Germanium Oxide on CVD Zeolites by Extended X-Ray Absorption Fine Structure and X-Ray Photoelectron Spectroscopy T. Hibino, M. Niwa, Y. Murakami and M. Sano Nuclear Magnetic Resonance Relaxation Studies on the Preferential Solvation of tris-Acetylacetonato-Chromium(rr1) in Bromofom-Carbon Tetrachloride Solutions Diffusion Coefficients for a Series of n-Alkanes in two Polar Solvents K. D. Bartle, A. A. Clifford, D. Mills and R. Moulder R. Brown and C. Kemball F. Ferranti and A. Indelli R. G. Compton, R. G. Harland and R.J. Northing P-L. Wang and L-P. HwangContents 2355 2369 238 1 2397 2405 2417 2427 2435 2445 2453 2465 2473 2481 2499 2507 2525 2535 2555 2563 2575 258 1 Comparison of Entropic and Enthalpic Components of the Barrier Symmetry Factor, b, for Proton Discharge at Liquid and Solid Hg in Relation to the Variation of Tafel Slopes and /3 with Temperature B. E. Conway and D. P. Wikinson Photolysis of Cyclotetrasilanes. Remarkable Dependence on Molecular Structure H. Shizuka, K. Murata, Y. Arai, K. Tonokura, H. Tanaka, H. Matsumoto, Y. Nagai, G. Gillette and R. West Reaction of Preadsorbed Methane with Oxygen over Magnesium Oxide at Low Temperatures T. Ito, T. Watanabe, T. Tashiro and K. Toi Bending Vibrations of OH Groups resulting from H, Dissociation on ZnO A. A.Tsyganenko, J. Lamotte, J. Saussey and J. C. Lavalley Effect of Solvent on the Reactions of Coordination Complexes. Part 8.-Kinetics of Solvolysis of cis-(Chloro)(ethanolamine)bis(ethylenediamine)- cobalt(II1) in Methanol-Water, Propan-2-01-Water and t-Butyl Alcohol-Water A. C. Dash and P. K. Das Isomeric Equilibria of Monosaccharides in Solution. Influence of Solvent and Temperature F. Franks, (in part) P. J. Lillford and G. Robinson Electron Transfer between a: and /3 Haem Groups in Haemoglobin. An Electron Spin Resonance Study M. C. R. Symons and F. A. Taiwo Application of Radiation and Electron Spin Resonance Spectroscopy to the Study of Ferry1 Myoglobin R. L. Petersen, M. C. R. Symons and F. A. Taiwo Silver(1)-Polyamine Systems in Dimethyl Sulphoxide. A Thermodynamic and Spectroscopic Investigation A.Cassol, P. Di Bernardo, P. Zanonato, R. Portanova, M. Tolazzi, G. Tomat, V. Cucinotta and D. Sciotto The Effect of Pressure on the Electrical Conductivity of Liquid Iodine, Iodine Chloride, Iodine Bromide and Bromine Trifluoride B. Cleaver and D. H. Condl yffe The Effect of Glucose on the Crystallization of Hydroxyapatite in Aqueous Solutions Electrochemical Characterisation of BaSn,-,Sb,O, Perovskites M. I. da Silva Pereira, M-J. B. V. Melo, F. M. A. da Costa, M. R. Nunes and L. M. Peter The Second Emission of the Uranyl Ion in Aqueous Solution M. D. Marcantonatos and M. M. Pawlowska Intermicellar Interactions and Micelle Size Distribution in Aqueous Solutions of Polyoxyethylene Surfactants T. Kato, S-i. Anzai, S. Takano and T.Seimiya Partial Oxidation of Methane over Oxide Catalysts. Comments on the Reaction Mechanism G. J. Hutchings, J. R. Woodhouse and M. S. Scurrell Quasi-elastic Neutron Scattering Study of Benzene Adsorbed in ZSM-5 H. Jobic, M. We and A. J. Dianoux AlPOJTiO, Catalysts. Part 2.-Structure, Texture and Catalytic Activity of Systems Precipitated with Ammonia or Ethene Oxide J. M. Campelo, A. Garcia, D. Luna, J. M. Marinas and M. S. Moreno Applicaton of Pitzer's Equations to Dissociation Constants of Ammonium Ion in Lithium Chloride-Sodium Chloride Mixtures M. Maeda, 0. Hisada, K. Ito and Y. Kinjo Enthalpic Interaction Coefficients of some Dipeptides Dissolved in N,N- Dimethylfonnamide Activity Coefficients for Aqueous Solutions of Potassium Succinate (K,Succ) at 25 "C M.A. Esteso, L. Fernandez-Merida, 0. M. Gonzalez-Diaz and F. F. Hernandez-Luis Perhydrotriphenylene Radical. An Initiator for Inclusion Polymerization as Characterized by Electron Spin Resonance Spectroscopy P. Sozzani, R. Scotti and F. Morazzoni E. Dalas and P. G. Koutsoukos A. H. Sijpkes and G. Somsen2587 2597 2605 2615 2625 2635 2641 2647 Con tents Solvation and Complexation of Copper(n) and Chloride Ions in 2,2,2- Trifluoroethanol-Dimethyl Sulphoxide Mixtures H. Suzuki, S. Ishiguro and H. Ohtaki Active Structures and Electronic States for Adsorption of CO, and NO on an Na/TiO,(l 10) Surface H. Onishi, T. Aruga, C. Egawa and Y. Iwasawa Quenching of the Luminescence of the Aqueous Gadolinium Ion by Nitrate and Thiocyanate J-J. Vuilleumier, M. Deschaux and M. D. Marcantonatos Detection and Quantitative Determination of the Composition of Bismuth Molybdate Phases by Various Spectroscopic Techniques R. Olier, G. Coudurier, M. El Jamal, M. Forissier and J. C. Vedrine Photophysics of the Excited Uranyl Ion in Aqueous Solutions. Part 6.- Quenching Effects of Aliphatic Alcohols M. E. D. G. Azenha, H. D. Burrows, S. J. Formosinho and M. de Graga M. Miguel Oxygen Adsorption on Ag Powder M. Bowker, P. Pudney and G. Roberts Induction of Mesoporosity in ALPO-5. Treatment with Silicon Tetrachloride C. R. Theocharis, M. R. Gelsthorpe and D. Yeates Corrigendum to Successive Addition of Electrons to Sodium Quinizarin-2- and -6-Sulphonate in Aqueous Solution. A Pulse and y-Radiolysis Study T. Mukherjee, E. J. Land, A. J. Swallow, P. M. Guyan and J. M. Bruce