首页   按字顺浏览 期刊浏览 卷期浏览 Direct Energy Supply for Initiation of Some Photochemical Reactions in Macromolecules
Direct Energy Supply for Initiation of Some Photochemical Reactions in Macromolecules

 

作者: TymishYu. Ogul'chansky,   LyudmilaO. Vretik,   ValeriyM.N. Yashchuk,   VolodymirG. Syromyatnikov,   OlexiyYu. Kolendo,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  （Taylor Available online 1998）
卷期: Volume 324, issue 1  

页码: 223-230

 

ISSN:1058-725X

 

年代: 1998

 

DOI:10.1080/10587259808047158

 

出版商: Taylor & Francis Group

 

关键词: functional macromolecule;direct electronic excitation energy transfer;Fries photorearrangement

 

数据来源: Taylor

 

摘要:

The possibility of using the direct electronic excitation energy transfer for energy supply to definite points of molecular systems for initiation of the chemical reactions or, on the contrary, for drainage of electronic excitation energy from the points of molecular systems suitable for reactions with the aim of their stabilization is examined. An analysis of Fries photorearrangement process in investigated compounds confirms the possibility of affecting the rate of Fries photorearrangement by means of electronic excitation energy supply.

 

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