Sydnon‐äthylene. III. Chemische Reaktionen elektronisch angeregter 4‐Styryl‐sydnone
作者:
Bernd‐Michael Neumann,
Hans‐Georg Henning,
Dieter Gloyna,
Joachim Sauer,
期刊:
Journal für Praktische Chemie
(WILEY Available online 1978)
卷期:
Volume 320,
issue 1
页码: 81-90
ISSN:0021-8383
年代: 1978
DOI:10.1002/prac.19783200110
出版商: WILEY‐VCH Verlag GmbH
数据来源: WILEY
摘要:
Sydnone Ethylenes. III. Chemical Reactions of Excited 4‐Styryl‐sydnonesDependent on the character of the substituents in the photo reactions of 4‐styryl sydnonesZ/E‐isomerism competes with CO2‐elimination. Excited p‐nitrostyryl sydnones exhibit a relatively strong degradation of the bond order in the CC region. Their quantum yields ofZ/E‐isomerism are therefore much higher than those of compounds with p‐substituents of lower acceptor effect. In these compounds the cleavage of the sydnone ring with elimination of carbon dioxide is favoured especially if a methyl group is in 3‐posi
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