Chemorheological studies on polymer degradation
作者:
Kenkichi Murakami,
Sumio Takasugi,
期刊:
Journal of Applied Polymer Science
(WILEY Available online 1977)
卷期:
Volume 21,
issue 1
页码: 55-63
ISSN:0021-8995
年代: 1977
DOI:10.1002/app.1977.070210105
出版商: Wiley Subscription Services, Inc., A Wiley Company
数据来源: WILEY
摘要:
AbstractThe degradation of dicumyl peroxide‐cured natural rubber was studied by the stress relaxation method. Experiments were carried out in air, in nitrogen, and by irradiation of UV light in the temperature range of 30–200°C. We attempted to divide factors of the degradation into two parts: that caused by heat and that by light, and to study the respective degradation quantitatively. The degradation caused by UV light in nitrogen was almost independent of temperature. However, the degradation caused by UV light in air increased with temperature and the rate of degradation caused by the interaction between light and oxygen was greater at high temperature than at low temperature. It was found that scission along main chains occurs for dicumyl peroxide‐cured natural rubber by photo‐oxidation as well as thermal o
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