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Ultrasonic Measurement of Vibrational, Rotational Isomeric, Structural and Shear Relaxation in Isobutyl Bromide

 

作者: A. E. Clark,   T. A. Litovitz,  

 

期刊: The Journal of the Acoustical Society of America  (AIP Available online 1960)
卷期: Volume 32, issue 10  

页码: 1221-1236

 

ISSN:0001-4966

 

年代: 1960

 

DOI:10.1121/1.1907887

 

出版商: Acoustical Society of America

 

数据来源: AIP

 

摘要:

Ultrasonic measurements of the longitudinal absorption and velocity and shear impedance were made over a large range of temperatures in the weakly associated liquid isobutyl bromide. Evidence was found for the coexistence of four different relaxation mechanisms. Above −50°C rotational isomeric relaxation exhibiting a single relaxation time was found. Vibrational relaxation also appears to be present with a relaxation time shorter than that usually found in nonassociated liquids. The dispersion and absorption data below −125°C showed that both shear and structural relaxation effects were present. The former was related to a distribution of relaxation times. The coexistence of these several relaxations is consistent with the concept that a weakly associated liquid should show relaxation behavior typical of both strongly and nonassociated liquids.

 

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