Energy level data are given for the atom and all positive ions of silicon (Z=14). These data have been critically compiled, mainly from published material on measurements and analyses of the optical spectra. We have derived or recalculated the levels for a number of the ions. In addition to the level value in cm−1and the parity, theJvalue and the configuration and term assignments are listed if known. Leading percentages from the calculated eigenvectors are tabulated or quoted wherever available. Ionization energies are given for all spectra. Key words: atomic energy levels; atomic ions; atomic spectra; electron configurations; ionization potentials; silicon.