Effects of Benzene on the1HNMR of α-Oxoketene Dithioacetals
作者:
Haifeng Zhang,
Jianjun Zhang,
Yintang Yang,
Qiuqing Yang,
Liping Yang,
Fengchuan Yang,
期刊:
Spectroscopy Letters
(Taylor Available online 1991)
卷期:
Volume 24,
issue 1
页码: 43-54
ISSN:0038-7010
年代: 1991
DOI:10.1080/00387019108018123
出版商: Taylor & Francis Group
关键词: ASIS effect;linear correlation;solvation;continuous field
数据来源: Taylor
摘要:
1HNMR spectra of the title compounds have been measured as the function of the mole fraction of benzene in the mixture solvent of benzene and CC14. As the mole fraction of benzene increases, the chemical shifts (δ) of two methyl groups in a molecule and of benzene gradually move upfield. The upfield shifts of different methyl groups in a molecule are not equal to one another. The Δδ of β-CH3is larger than that of α-CH3. Thus, the two lines appear to coalesce at a certain concentration and to cross over with the increment of the proportion of benzene. All of the chemical shifts can be related with a linear equation (δ=A+BX). Where, X is the mole fraction of benzene in the mixture solvent. The correlation coefficients R are approximately equal to 1.
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