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Fourier transform infrared spectrometer for a single aerosol particle

 

作者: Gideon Sageev Grader,   Richard C. Flagan,   John H. Seinfeld,   Stephen Arnold,  

 

期刊: Review of Scientific Instruments  (AIP Available online 1987)
卷期: Volume 58, issue 4  

页码: 584-587

 

ISSN:0034-6748

 

年代: 1987

 

DOI:10.1063/1.1139220

 

出版商: AIP

 

数据来源: AIP

 

摘要:

A spectrometer is reported here for obtaining the infrared spectrum of a single aqueous aerosol particle by a Fourier transform technique. The particle is held in an electrodynamic balance and irradiated simultaneously by the infrared output from a Michelson interferometer and the visible light from a dye laser. The size of the particle is modulated by chopping the IR beam, and the resulting visible scattered light fluctuation is detected at 90° with a photomultiplier tube. The amplitude of the scattered light fluctuation is measured with a lock‐in amplifier at each interferometer mirror position. The electronic circuitry for stepping the interferometer mirror is presented and discussed. Inverting the lock‐in signal by a discrete fast Fourier transform routine (FFT) yields the particle absorption spectrum. The resulting spectrum for an (NH4)2SO4droplet is presented.

 

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