Electrochemical Behaviour Study of Mixed Ligand Complexes of Diaminopropane and Phthalate with Cd(II) Using Differential Pulse Polarography and Cyclic Voltammetry Techniques
作者:
H.M. Killa,
H.A. Dessouki,
M.G. Abd El-Wahed,
M. Zaky,
期刊:
Analytical Letters
(Taylor Available online 1987)
卷期:
Volume 20,
issue 12
页码: 2055-2063
ISSN:0003-2719
年代: 1987
DOI:10.1080/00032718708078046
出版商: Taylor & Francis Group
关键词: Diaminopropane;Phthalate;Cyclic Voltammetry;Differential Pulse Polarography
数据来源: Taylor
摘要:
Differential pulse(d. p.)polarography has been used to study the simple and mixed ligand complexes of 1, 3 diaminopropane (DAMP) and phthalate(PHLT) with Cd(II) at constant ionic strength (u= 1.0 M NaNO3) at 25°C The overall formation constants of simple and mixed complexes were calculated. The reduction of the simple and mixed species is reversible and diffusion controlled. The postive values of the mixing constants for the mixed-ligand complexes indicate that the mixed-ligand complexes are more stable than simple binary complexes. The equilibria between the various mixed-ligand species in the solution and their equilibrium are given.
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