Ozonolysis of unsaturated fatty acids. II. Esterification of the total products from the oxidative decomposition of ozonides with 2,2-dimethoxypropane
作者:
John D. Castell,
R. G. Ackman,
期刊:
Canadian Journal of Chemistry
(NRC Available online 1967)
卷期:
Volume 45,
issue 13
页码: 1405-1410
ISSN:0008-4042
年代: 1967
DOI:10.1139/v67-232
出版商: NRC Research Press
数据来源: NRC
摘要:
The total acidic products from the performic acid oxidation of the ozonide of methyl oleate formed in methanol may be esterified directly in a few hours with 2,2-dimethoxypropane. The ester concentrations are adequate for the determination of the positional isomers of monoethylenic fatty acids directly from the reaction mixture, using a hydrogen flame ionization gas–liquid chromatography detector. Dimethyl sulfoxide was not required to prevent the breakdown of 2,2-dimethoxypropane under the conditions employed.
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