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Approximate Relationships for the Thermodynamic Properties of Hydrocarbon-Air Combustion Products

 

作者: MICHAEL K. MARTIN,   JOHN B. HEYWOOD,  

 

期刊: Combustion Science and Technology  (Taylor Available online 1977)
卷期: Volume 15, issue 1-2  

页码: 1-10

 

ISSN:0010-2202

 

年代: 1977

 

DOI:10.1080/00102207708946765

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Abstract-A model is presented by means of which the enthalpy (h) and density (p) of the products of hydrocarbonair combustion can be calculated as functions of pressure (P), temperature (T). and equivalence ratio (φ) for a given C: H ratio of the fuel, and N: 0 ratio of Ihe oxidizer. By direct differentiation, the partial derivatives of h and p with respect to P, T, and φ can also be calculated. Results of calculations using this model are compared with results from a detailed thermochemical equilibrium calculation incorporating over 40 species, and it is shown that accuracy of the approximate model is acceptable over most conditions of interest in typical combustion calculations for a range of practical fuels. The principal advantage of this method is computational speed; it thus has obvious utility in, for example, internal combustion engine performance calculations.

 

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