Mechanical relaxation in polypropylene as a function of polymorphism and degree of lamella orientation
作者:
J. M. Crissman,
期刊:
Journal of Polymer Science Part A‐2: Polymer Physics
(WILEY Available online 1969)
卷期:
Volume 7,
issue 2
页码: 389-404
ISSN:0449-2978
年代: 1969
DOI:10.1002/pol.1969.160070210
出版商: John Wiley&Sons, Inc.
数据来源: WILEY
摘要:
AbstractMechanical relaxation data as a function of temperature (ca. 1 Hz) have been obtained for several samples of isotactic polypropylene crystallized from the melt, which exhibit both α and β forms as well as varying degrees of lamella orientation. The samples ranged in morphology from an unoriented sample showing only the α form to one highly oriented having approximately 90 per cent the β form. Results for the logarithmic decrement Δ and loss modulusG″ are that the low temperature (ca. −75°C) and glass temperature (ca. 0°C) relaxations show little or no sensitivity to orientation in the α form, but that the intensity of the two processes is different in the α form than in the β form for samples of nearly equal overall per cent crystallinity. In both Δ andG″, the low‐temperature peak decreased and the glass temperature peak increased in intensity as the fraction of β form crystallinity present increased. Data for the high‐temperature relaxation (ca. 80°C) indicate a dependence upon orientation and/or crystal form in addition to a dependence upon
点击下载:
PDF
(1266KB)
返 回