Rates of OH radical reactions. XII. The reactions of OH withcC3H6,cC5H10, andcC7H14. Correlation of hydroxyl rate constants with bond dissociation energies
作者:
Gurvinder S. Jolly,
George Paraskevopoulos,
Donald L. Singleton,
期刊:
International Journal of Chemical Kinetics
(WILEY Available online 1985)
卷期:
Volume 17,
issue 1
页码: 1-10
ISSN:0538-8066
年代: 1985
DOI:10.1002/kin.550170102
出版商: John Wiley&Sons, Inc.
数据来源: WILEY
摘要:
AbstractAbsolute rate constants for H‐atom abstraction by OH radicals from cyclopropane, cyclopentane, and cycloheptane have been determined in the gas phase at 298 K. Hydroxyl radicals were generated by flash photolysis of H2O vapor in the vacuum UV, and monitored by time‐resolved resonance absorption at 308.2 nm [OH(A2Σ+→X2Π)]. The rate constants in units of cm3mol−1s−1at the 95% confidence limits were as follows:k(cC3H6) = (3.74 ± 0.83) × 1010,k(cC5H10) = (3.12 ± 0.23) × 1012,k(cC7H14) = (7.88 ± 1.38) × 1012. A linear correlation was found to exist between the logarithm of the rate constant per CH bond and the corresponding bond dissociation energy for several classes of organic compounds with equivalent CH bonds. The correlation favors a value of D(cC
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