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Remote scanning ultraviolet detection for capillary gas chromatography

 

作者: Darryl J. Bornhop,   Louis Hlousek,   Murray Hackett,   Houle Wang,   Glenn C. Miller,  

 

期刊: Review of Scientific Instruments  (AIP Available online 1992)
卷期: Volume 63, issue 1  

页码: 191-201

 

ISSN:0034-6748

 

年代: 1992

 

DOI:10.1063/1.1142956

 

出版商: AIP

 

数据来源: AIP

 

摘要:

A remote flow cell has been interfaced to a scanning uv‐visible absorbance detector for the detection of gas chromatography (GC) analytes. The unique optical bench, detection scheme, and thermal control allow low‐noise operation at flow cell temperatures of 350 °C. Noise of 1×10−5a.u. (peak to peak over a 1‐min period) and drift at the 1×10−4a.u./h level facilitate detection of coumarin in the gas phase at 40 pg/s. Flow cell volume was optimized for use with capillary GC columns. An effective band pass of <3 nm provides spectral resolution which shows solute absorbance fine structure to aid in compound identification.

 

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