Remote scanning ultraviolet detection for capillary gas chromatography
作者:
Darryl J. Bornhop,
Louis Hlousek,
Murray Hackett,
Houle Wang,
Glenn C. Miller,
期刊:
Review of Scientific Instruments
(AIP Available online 1992)
卷期:
Volume 63,
issue 1
页码: 191-201
ISSN:0034-6748
年代: 1992
DOI:10.1063/1.1142956
出版商: AIP
数据来源: AIP
摘要:
A remote flow cell has been interfaced to a scanning uv‐visible absorbance detector for the detection of gas chromatography (GC) analytes. The unique optical bench, detection scheme, and thermal control allow low‐noise operation at flow cell temperatures of 350 °C. Noise of 1×10−5a.u. (peak to peak over a 1‐min period) and drift at the 1×10−4a.u./h level facilitate detection of coumarin in the gas phase at 40 pg/s. Flow cell volume was optimized for use with capillary GC columns. An effective band pass of <3 nm provides spectral resolution which shows solute absorbance fine structure to aid in compound identification.
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