Ionic Polymerization of Vinyl Aromatic Monomers
作者:
JamesM. Pearson,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1975)
卷期:
Volume 9,
issue 6
页码: 1029-1046
ISSN:0022-233X
年代: 1975
DOI:10.1080/00222337508081506
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The ionic polymerization of vinyl monomers possessing aromatic and heterocyclic functional groups has not been studied in any systematic fashion. Only in a few isolated cases have detailed mechanistic and structural studies been reported. The anionic polymerization of a number of vinylanthracene monomers has recently been investigated and some rationalization of this system is presented. The cationic and anionic polymerization of the N-, 3-, and 2-vinylcarbazole series of monomers is discussed in some detail. The important role of vinyl aromatic/vinyl heterocyclic monomers, i.e., diphenylethylene and the vinylcarbazoles, in elucidating the mechanistic aspects of cationic polymerization, “change transfer” polymerization, and photoionic polymerization is considered.
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