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Supression of size effects in ferroelectric films

 

作者: SeshuB. Desu,   OrestG. Vendik,  

 

期刊: Integrated Ferroelectrics  (Taylor Available online 2000)
卷期: Volume 28, issue 1-4  

页码: 175-192

 

ISSN:1058-4587

 

年代: 2000

 

DOI:10.1080/10584580008222230

 

出版商: Taylor & Francis Group

 

关键词: SrTiO3;ferroelectric films;size effects;oxide electrodes;suppression;boundary conditions

 

数据来源: Taylor

 

摘要:

It is widely reported that the dielectric permittivity of ferroelectric films decreases with decreasing film thickness, and understanding and controlling these size effects are very important for charge storage application of these films. By combining phenomenological theory with careful experimental work, we have shown that the form of the boundary condition for the polarization plays a decisive role in the manifestation of size effects in ferroelectric films. We have taken two extreme boundary conditions to prove our point. For the case normal electrodes, it is assumed that the boundary condition for the component of polarization vector at the ferroelectric/electrode interface is P = 0. This case corresponds to the presence of a strong edge field, resulting in “freezing out” of the ferroelectric polarization at the interface and thus exhibiting severe size effects. However, if one utilizes conductiveoxide electrodes that are ferroelectric in naturethe polarization would not vanish at the ferroelectric/electrode interface and therefore the size effects are largely suppressed. To prove our point and to eliminate grain size, stress, and compositional effects, epitaxial SrTiO3thin films with stoichiometric composition on SrTiO3single crystal substrates were investigated. In fact, the experimental data also indicates that the use of ferroelectric electrodes indeed suppresses the size effects.

 

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