Anomalies in Hg-Tl Amalgam Viscosity
作者:
M.Bosco Masera,
I. Maio,
期刊:
Physics and Chemistry of Liquids
(Taylor Available online 1991)
卷期:
Volume 22,
issue 4
页码: 213-216
ISSN:0031-9104
年代: 1991
DOI:10.1080/00319109108030623
出版商: Taylor & Francis Group
关键词: Amalgam;binary mixture
数据来源: Taylor
摘要:
Some anomalies have been found in the Hg-TI amalgam viscosity variation with temperature and component concentrations. An intermetallic compound formation or a miscibility gap in the amalgam state diagram are probably responsible for the anomalous behaviour. Viscosity measurements have been carried out through the toroidal oscillating viscosimeter described in Ref. 1, while previous results on Hg-TI viscosity are reported in Refs. 2,3,4. At the present time, the anomalies were mainly observed at 28.2% at. T1, which belongs to a composition interval where the amalgam behaviour is particularly complex; two intermetallic compounds are located at 28.57% and at 33.33% at. TI while their maxima in the state diagram are so flat to be hardly detectable. Anomalous results were obtained well above the solidification temperature and, though they are not evidence for a phase transition to an in-homogeneous liquid state or to an intermetallic compound, such a transition is a likely cause of the anomalous behaviour.
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