Calibration of Sm:YAG as an alternate high‐pressure scale
作者:
Q. Bi,
J. M. Brown,
Y. Sato‐Sorensen,
期刊:
Journal of Applied Physics
(AIP Available online 1990)
卷期:
Volume 68,
issue 10
页码: 5357-5359
ISSN:0021-8979
年代: 1990
DOI:10.1063/1.347031
出版商: AIP
数据来源: AIP
摘要:
The pressure‐induced wavelength shift of a laser‐excited fluorescence in samarium‐doped yttrium aluminum garnet (Sm:YAG) was compared with that of ruby to 26 GPa at room temperature. Because the fluorescence wavelength for Sm:YAG has a negligible temperature dependence, it provides a better pressure scale for diamond anvil cell applications than ruby under high‐temperature conditions. However, the overall intensity of the Sm:YAG fluorescence is less than that for ruby. A Gaussian–Lorentzian profile was chosen to analyze the fluorescence spectra. The Sm:YAG fluorescence wavelength exhibits an approximately linear pressure dependence (3.07±0.45 A˚/GPa) only to 20 GPa at room temperature. A polynomial fit for all data to 26 GPa givesP(GPa)=−10 280(&lgr;/&lgr;0−1)2+2085(&lgr;/&lgr;0−1), with a rms misfit of 0.14 GPa.<squeeze>
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