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Cyclopolymerization. V. The13C Spectrum and Structure of the Low Molecular Weight Product from the Reaction of N-Methyl-N,N-diallylamine with Azobisisobutyronitrile

 

作者: S.R. Johns,   R.I. Willing,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  （Taylor Available online 1975）
卷期: Volume 9, issue 1  

页码: 169-181

 

ISSN:0022-233X

 

年代: 1975

 

DOI:10.1080/00222337508068653

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

A study of the13C chemical shift data and of the shifts induced by Eu(dpm)3has shown that the aminoketone formed in the reaction of N-methyl-N,N-diallylamine with cyanoisopropyl radicals is 2,6,6-trimethyl-cis-perhydroisoindolid-5-one (1a, R = O). The13C NMR spectrum in the presence of acid reveals the existence of two protonated forms of this compound.

 

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