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Field sums for extended dipoles in ferroelectric polymers

 

作者: R. Al‐Jishi,   P. L. Taylor,  

 

期刊: Journal of Applied Physics  (AIP Available online 1985)
卷期: Volume 57, issue 3  

页码: 897-901

 

ISSN:0021-8979

 

年代: 1985

 

DOI:10.1063/1.334689

 

出版商: AIP

 

数据来源: AIP

 

摘要:

A previously described method for calculating the Lorentz factorLfor orthorhombic polar crystals is modified to allow discussion of dipoles of finite size. In this approach, the field due to a lattice of point charges ±qseparated by a distancedis calculated. The Lorentz factor, which relates the field at a lattice site to the macroscopic polarization, is found as a function of the dipole lengthd, and is seen to vary appreciably with changes in the separation between the charges. Assumption of a value of 1/3 forLcan thus lead to significant errors in determining the self‐consistent polarization of crystals consisting of polarizable molecules.

 

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