Singlet distribution for dense fluid non-equilibria
作者:
P.M. Allen,
G.H.A. Cole,
期刊:
Molecular Physics
(Taylor Available online 1968)
卷期:
Volume 15,
issue 6
页码: 549-555
ISSN:0026-8976
年代: 1968
DOI:10.1080/00268976800101451
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The theory of Prigogine is applied to the deduction of a general kinetic equation for the singlet phase distribution for a fluid not in equilibrium. The intermolecular interaction is assumed to have the form of the sum of constituent pair forces; but the pair force itself is supposed to have a realistic form and any restriction to a hard-core repulsion is explicitly avoided. The general equation for the singlet distribution is set down in §5 and its derivation involves the consideration of the associated diagrams in numerical terms. The effects of the short-range (repulsive) and long-range (collective) molecular interactions are summed separately even although the hard-core repulsion of the pair potential is relaxed. The present paper is the natural extension of a previous communication by the present authors and of the earlier work of Rice and Allnatt.
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