Solid-State Polymerization in Binary Component Systems at Low Temperature
作者:
Kenkichi Ishigure,
Yoneho Tabata,
Keichi Oshima,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1967)
卷期:
Volume 1,
issue 4
页码: 591-601
ISSN:0022-233X
年代: 1967
DOI:10.1080/10601326708053996
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Radiation-induced polymerization in binary component systems of acrylonitrile-methacrylonitrile and acrylonitrile-vinyl acetate was studied at −196°C. A mixture of two-component homopolymers was obtained from the acrylonitrile-methacrylonitrile system, which forms a eutectic mixture. When the mixture of acrylonitrile with vinyl acetate is cooled quickly from room temperature, a glassy state can be obtained. It was found that the copolymerization is possible in the glassy state at −196°C, and the monomer reactivity ratios were determined asr1= 6.0 andr2= 0.2 (M1= acrylonitrile), which coincides with the reported values on the radical copolymerization at room temperature.
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