Die Reduktion von Azulen mit Natrium zum Kontaktionen‐Tripel [Dinatrium‐(1,1′,6,6′‐Tetrahydro‐6,6′‐bi(azulen)‐1,1′‐diid)–bis (diglyme)]∞
作者:
Hans Bock,
Claudia Arad,
Christian Näther,
Ilka Göbel,
期刊:
Helvetica Chimica Acta
(WILEY Available online 1996)
卷期:
Volume 79,
issue 1
页码: 92-100
ISSN:0018-019X
年代: 1996
DOI:10.1002/hlca.19960790110
出版商: WILEY‐VCH Verlag GmbH
数据来源: WILEY
摘要:
The Sodium Reduction of Azulene to the Contact‐Ion Triple [Disodium‐(1,1′,6,6′‐Tetrahydro‐6,6′‐bi(azulene)‐1,1′‐diide)–bis(diglyme)]∞Colorless air‐sensitive single crystals can be grown from a diglyme solution after the reduction of azulene by a Na‐metal mirror. Structure determination at 150 K reveals a dimer dianion, in which the seven‐membered rings are connected in 6,6′‐positions and doubly diglyme‐solvated Na+counter cations η5‐coordinate to the five‐membered rings. Based on preceding cyclovoltammetric measurements in aprotic azulene solutions as well as on extensive MNDO enthalpy of formation calculations, a proposal is forwarded how possibly the contact ion tr
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