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ChemInform Abstract: Molybdenum Complexes of 1,2‐Bis(diphenylphosphino)benzene. Mononuclear Molybdenum(II) Species Formed by Facile Metal‐Metal Bond Cleavage of the (Mo‐Mo Quadruple Bond)4+ Core.

 

作者: M. BAKIR,   F. A. COTTON,   M. M. CUDAHY,   C. Q. SIMPSON,   T. J. SMITH,   E. FIORE VOGEL,   R. A. WALTON,  

 

期刊: ChemInform  （WILEY Available online 2016）
卷期: Volume 19, issue 47  

页码: -

 

ISSN:0931-7597

 

年代: 2016

 

DOI:10.1002/chin.198847257

 

出版商: WILEY‐VCH Verlag GmbH

 

数据来源: WILEY

 

摘要:

AbstractThe quadruply bonded dimolybdenum(II) complexes (I) and also (NH4)5(Mo2Cl9)·H2O react with the title diphosphine (II) in MeOH at room temp. to afford the binuclear α‐complexes (III) which do not isomerize to the β isomers.

 

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