Temperature Dependence of Ultra‐Low‐Frequency Dielectric Relaxation of Barium Titanate Ceramic
作者:
Fan Chu,
Hong‐Tao Sun,
Liang‐Ying Zhang,
Xi Yao,
期刊:
Journal of the American Ceramic Society
(WILEY Available online 1992)
卷期:
Volume 75,
issue 11
页码: 2939-2944
ISSN:0002-7820
年代: 1992
DOI:10.1111/j.1151-2916.1992.tb04368.x
出版商: Blackwell Publishing Ltd
数据来源: WILEY
摘要:
Based on a linear voltage ramp method, ultraslow dielectric relaxation of undoped BaTiO3ceramic has been carefully measured over the temperature range between − 180° and +120°C. Temperature dependence of the dielectric constant in the frequency range from 10−5to 10−1Hz can be obtained using Kramers–Kronig equations. Close to the Curie temperature, the dielectric constant increases so rapidly that the Curie peak is overwhelmed. Two kinds of relaxation processes were observed in this experiment. Ferroelectric domain and mobile charge are proposed to be responsible for the relaxation over the temperature range. With temperature increasing, Maxwell–Wagner relaxation associated with mobile charge gradually dominates. From relaxation time constants at various temperatures, relaxation activation energies about 0.06 and 0.09 eV are
点击下载:
PDF
(537KB)
返 回